About Creep-enabled 3d solid-state lithium-metal battery
Existing all-solid-state Li-metal batteries suffer attacks by the chemically aggressive and mechanically stressful Li metal. Li metal is a soft crystal and may exhibit either displacive or diffusive deformation. Here.
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About Creep-enabled 3d solid-state lithium-metal battery video introduction
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5 FAQs about [Creep-enabled 3d solid-state lithium-metal battery]
What is a creep-enabled battery engine?
The successful construction of a creep-enabled battery engine opens a new avenue toward high-density, electrochemically and mechanically robust all-solid-state Li-metal batteries.
What is a 3D Li-foil battery?
The 3D porous MIEC/ELI structure is combined with Li metal to form the anode of the all-solid-state battery. Compared with the current 2D Li-foil anodes, the multiple electrochemically engineered interfaces endow the creep-enabled 3D anode with distinct kinetics of Li deposition and stripping.
What is the creep mechanism of Li metal?
Several creep mechanisms exist for metals. The creep strain rate ε (T, σ) of Li metal could possibly be driven by the dislocation creep (power-law creep) or diffusional creep (linear creep), according to the deformation mechanism map of metals (Figure 3 B).
Can a 3D solid-state Li-metal battery achieve a gravimetric energy density?
With those practical low-cost and viable approaches for further optimizations, we estimate that a practical pouch cell of the creep-enabled 3D solid-state Li-metal battery can attain a gravimetric energy density of over 500 Wh kg –1 and a volumetric energy density over 800 Wh L –1.
What if diffusional creep mechanisms are operative?
If diffusional creep mechanisms, either the lattice-diffusional Nabarro-Herring creep or interfacial/surface-diffusional Coble creep, are operative, then ε (T, σ) ∝ σ, the viscosity η would depend on T and grain size, but not on σ, and Li metal would behave like a Newtonian fluid.